Product ID:FREON TF
MSDS Date:07/25/1990
FSC:6850
NIIN:00-105-3084
MSDS Number: BPHFR

Emergency Phone: 408-435-8700 OR 303-338-5651

Info Phone: 408-435-8700

Cage: 87664

Telephone: 206-447-5911/800-424-9300(CHEMTREC)

Cage: 87664

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: >99%

OSHA PEL 1000PPM/1250STEL

ACGIH TLV: 1000PPM/1250STEL9192

LD50 LC50 Mixture:LD50 (ORAL RAT) IS 43 G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: VAPORS ARE HEAVIER THAN AIR AND
CAN CAUSE SUFFOCATION BY REDUCING OXYGEN AVAILABLE FOR BREATHING.
BREATHING VAPORS PLUS EPINEPHRIN TYPE DRUGS MAY CAUSE CARDIAC
IRREGULARITIES. CHRONIC: NO SPEC IFIC INFORMATION AVAILABLE.
Explanation of Carcinogenicity:NONE OF THE CHEMICALS IN THIS PRODUCT IS
LISTED BY IARC, NTP OR OSHA AS A CARCINOGEN.
Effects of Overexposure:INHALE: LIGHT-HEADEDNESS, GIDDINESS, SHORTNESS
OF BREATH, NARCOSIS, CARDIAC IRREGULARITIES, UNCONSCIOUSNESS OR
DEATH. EYE: IRRITATION. SKIN:NOTHING WITH BRIEF EXPOSURE;BUT
POSSIBLE IRRITATION AFTER PR OLONGED CONTACT. INGEST: LARGE
QUANTITIES MAY CAUSE NAUSEA AND VOMITING.
Medical Cond Aggravated by Exposure:CARDIOVASCULAR DISEASE MAY BE
AGGRAVATED.

First Aid:INHALATION: REMOVE SUBJECT TO FRESH AIR. MAINTIAN BREATHING.
EYE: FLUSH WITH PLENTY OF WATER FOR 15 MINUTES. GET IMMEDIATE
MEDICAL ATTENTION. SKIN: WASH WITH SOAP AND WATER. REMOVE
CONTAMINATED CLOTHI NG AND SHOES. IF IRRITATION PERSISTS, SEE DR.
INGESTION: DO NOT INDUCE VOMITING. GET IMMEDIATE MEDICAL ATTENTION.
NOTHING BY MOUTH IF UNCONSCIOUS OR CONVULSING.

Flash Point:NONE
Extinguishing Media:THIS MATERIAL IS NOT COMBUSTABLE. USE
EXTINGUISHING MEDIA APPPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD WEAR SCBA & FULL
PROTECTIVE CLOTHING. USE WATER SPRAY TO COOL NEARBY CONTAINERS &
STRUCTURES EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:EXTINGUISH ALL NEARBY SOURCES OF IGNITION
SINCE VAPORS DECOMPOSE TO HAZARDOUS PRODUCTS AT HIGH TEMPERATURES.

Spill Release Procedures:WIPE OR SOAK UP SMALL SPILLS WITH PAPER TOWEL
OR INERT ABSORBANT. DIKE TO RETAIN LARGE SPILLS. VACUUM UP FREE
LIQUID. REMOVE RESIDUE WITH INERT ABSORBANT. PLACE IN DOT DISPOSAL
CONTAINER. KEEP OUT OF SEWERS,STORM DRAINS, SURFACE WATERS, SOIL.
Neutralizing Agent:NO INFORMATION GIVEN ON MSDS BY SUPPLIER

Handling and Storage Precautions:STORE IN COOL, DRY, WELL VENTILATED
AREA. KEEP CONTAINERS CLOSED. STORE AWAY FROM OTHER CHEMICALS. DO
NOT USE PRESSURE TO EMPTY CONTAINER.
Other Precautions:'EMPTY' CONTAINERS MAY CONTAIN RESIDUE OR VAPOR.
TREAT THEM WITH THE RESPECT DUE FULL ONES. DO NOT CUT,WELD,ETC. ON
THEM. VAPORS ARE HEAVIER THAN AIR & COLLECT IN LOW PLACES. DO NOT
ENTER WHERE VAPORS ARE EXPECTED W/O SCBA & OBSERVER.

Respiratory Protection:WEAR NIOSH APPROVED SCBA OR SUPPLIED AIR
RESPIRATOR IF CONDITIONS OF USE GENERATE VAPORS OR MISTS.
Ventilation:MECHANICAL (GENERAL) VENTILATION CAPEABLE OF MAINTAINING
EMISSIONS AT THE POINT BELOS THE PEL.
Protective Gloves:RUBBER
Eye Protection:CHEMICAL SAFETY GOGGLES
Other Protective Equipment:SAFETY SHOWER AND EYE BATH. LONG SLEEVED
SHIRT, TROUSERES, SAFETY SHOES, RUBBER APRON.ED OR REPEATED
CONTACT.
Work Hygienic Practices:MFR: ? HMIS:USE GOOD CHEMICAL HYGIENE
PRACTICE. AVOID UNNECESSARY CONTACT. WASH THOROUGHLY BEFORE EATING
OR DRINKING.
Supplemental Safety and Health
MSDS RECEIVED FROM NAVY (FOCAL POINT N). NAVY IDENTIFIED NSN.

HCC:V2
NRC/State Lic Num:NONE
Boiling Pt:=47.8C, 118.F
Melt/Freeze Pt:=-35.C, -31.F
Vapor Pres:334 MM
Vapor Density:2.9
Spec Gravity:1.57
Evaporation Rate & Reference:>1 (BUTYL ACETATE=1)
Solubility in Water:NIL
Appearance and Odor:CLEAR, COLORLESS LIQUID WITH SLIGHT ETHEREAL ODOR.

Stability Indicator/Materials to Avoid:YES
ALKALIS, OXIDIZING MATERIALS, WATER & MOIST AIR, ALKALI OR ALKALINE
EARTH METALS, ALUMINUM OR ZINC.
Stability Condition to Avoid:OPEN FLAMES, WELDING ARCS, OR OTHER HIGH
TEMPERATURE SOURCES WHICH MAY INDUCE THERMAL DECOMPOSITION.
Hazardous Decomposition Products:MAY LIBERATE CARBON MONOXIDE, CARBON
DIOXIDE, HYDROGEN CHLORIDE, CHLORINE, PHOSGENE, OR HYDROGEN
FLOURIDE.

Waste Disposal Methods:DISPOSE OF CONTAMINATED PRODUCT AND MATERIALS
USED IN CLEANING UP SPILLS AND LEAKS IN A MANNER APPROVED FOR THIS
MATERIAL.CONSULT APPROPRIATE FEDERAL STATE AND LOCAL REGULATIORY
AGENCIES TO ACERTAIN P ROPER DISPOSAL PROCEDURES.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.